Total synthesis of (-)-dysiherbaine.
نویسندگان
چکیده
The enantioselective synthesis of (-)-dysiherbaine (1) has been established with efficiency via a unique synthetic strategy involving the desymmetrization of 2-substituted glycerol to install a quaternary chiral carbon, which induces further stereochemistry in the bicyclic perhydrofuropyran through mercuriocyclization and epoxidation.
منابع مشابه
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عنوان ژورنال:
- Chemical communications
دوره 48 50 شماره
صفحات -
تاریخ انتشار 2012